Commonly occurring product ions for PA(18:4(9E,11E,13E,15E)/23:0) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
765.5440
Precursor ion [M-H]-
507.3456
Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
489.3351
Neutral loss of sn1 RCOOH group from [M-H]-
429.2048
Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
411.1942
Neutral loss of sn2 RCOOH group from [M-H]-
353.3425
sn2 RCOO- ion
275.2017
sn1 RCOO- ion
231.2118
Loss of CO2 from sn1 RCOO- ion (PUFA)
171.0064
Glycerol-3-phosphate ion
152.9958
Glycerol-3-phosphate ion with loss of H2O
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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