Commonly occurring product ions for PA(20:0/22:5(4Z,7Z,10Z,13Z,16Z)) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
777.5440
Precursor ion [M-H]-
483.2517
Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
465.2987
Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
465.2412
Neutral loss of sn1 RCOOH group from [M-H]-
447.2881
Neutral loss of sn2 RCOOH group from [M-H]-
329.2486
sn2 RCOO- ion
311.2956
sn1 RCOO- ion
285.2588
Loss of CO2 from sn2 RCOO- ion (PUFA)
171.0064
Glycerol-3-phosphate ion
152.9958
Glycerol-3-phosphate ion with loss of H2O
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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