Commonly occurring product ions for PC(O-18:0/22:4(7Z,10Z,13Z,16Z))) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
858.6149
Precursor ion [M.chloride]-
808.6226
Loss of CH3 and chloride from precursor ion
737.5491
Loss of choline and chloride from precursor ion
494.3616
Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
476.3510
Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
405.2775
Loss of choline, chloride and neutral loss of sn2 RCOOH group from precursor ion
331.2643
sn2 RCOO- ion
287.2744
Loss of CO2 from sn2 RCOO- ion (PUFA)
224.0693
Glycerophosphocholine with loss of CH3 and H2O
168.0431
Phosphocholine with loss of CH3
152.9958
Glycerol-3-phosphate ion with loss of H2O
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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