Commonly occurring product ions for PG(14:1(9Z)/15:1(9Z))) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
675.4243
Precursor ion [M-H]-
601.3875
Loss of glycerol from precursor ion
467.2416
Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
453.2259
Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
449.2310
Neutral loss of sn1 RCOOH group from [M-H]-
435.2153
Neutral loss of sn2 RCOOH group from [M-H]-
393.2048
Loss of sn1 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
379.1891
Loss of sn2 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
375.1942
Neutral loss of sn1 RCOOH group and glycerol from [M-H]-
361.1786
Neutral loss of sn2 RCOOH group and glycerol from [M-H]-
245.0432
Glycerophosphoglycerol ion
239.2017
sn2 RCOO- ion
227.0326
Glycerophosphoglycerol ion -H2O
225.1860
sn1 RCOO- ion
209.0221
Glycerophosphoglycerol ion -2H2O
152.9958
Glycerol-3-phosphate ion with loss of H2O
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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