Commonly occurring product ions for PG(19:0/18:4(6Z,9Z,12Z,15Z))) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 783.5182 | Precursor ion [M-H]- |  |
| 709.4814 | Loss of glycerol from precursor ion |  |
| 525.3198 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 507.3092 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 503.2416 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 485.2310 | Neutral loss of sn1 RCOOH group from [M-H]- |  |
| 451.2830 | Loss of sn2 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]- |  |
| 433.2725 | Neutral loss of sn2 RCOOH group and glycerol from [M-H]- |  |
| 429.2048 | Loss of sn1 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]- |  |
| 411.1942 | Neutral loss of sn1 RCOOH group and glycerol from [M-H]- |  |
| 297.2799 | sn1 RCOO- ion |  |
| 275.2017 | sn2 RCOO- ion |  |
| 245.0432 | Glycerophosphoglycerol ion |  |
| 231.2118 | Loss of CO2 from sn2 RCOO- ion (PUFA) |  |
| 227.0326 | Glycerophosphoglycerol ion -H2O |  |
| 209.0221 | Glycerophosphoglycerol ion -2H2O |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |