Commonly occurring product ions for PG(O-22:1(9Z)/18:2(9Z,11Z)) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
813.6015Precursor ion [M-H]-
739.5647Loss of glycerol from precursor ion
551.3718Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
533.3613Neutral loss of sn2 RCOOH group from [M-H]-
477.3351Loss of sn2 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
459.3245Neutral loss of sn2 RCOOH group and glycerol from [M-H]-
279.2330sn2 RCOO- ion
245.0432Glycerophosphoglycerol ion
227.0326Glycerophosphoglycerol ion -H2O
209.0221Glycerophosphoglycerol ion -2H2O
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases