Commonly occurring product ions for PI(18:0/28:0) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 1005.7377 | Precursor ion [M-H]- |  |
| 843.6848 | Loss of inositol from [M-H]- |  |
| 739.4767 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 721.4661 | Neutral loss of sn1 RCOOH group from [M-H]- |  |
| 599.3202 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 581.3096 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 577.4239 | Loss of sn1 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 559.4133 | Neutral loss of sn1 RCOOH group and inositol from [M-H]- |  |
| 437.2674 | Loss of sn2 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 423.4208 | sn2 RCOO- ion |  |
| 419.2568 | Neutral loss of sn2 RCOOH group and inositol from [M-H]- |  |
| 315.0487 | Glycerophosphoinositol -H2O |  |
| 297.0381 | Glycerophosphoinositol -2H2O |  |
| 283.2643 | sn1 RCOO- ion |  |
| 259.0225 | Inositol phosphate ion |  |
| 241.0119 | Inositol phosphate ion - H2O |  |
| 223.0013 | Inositol phosphate ion - 2 H2O |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |