Commonly occurring product ions for PI(35:0/22:5(4Z,7Z,10Z,13Z,16Z)) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 1149.8316 | Precursor ion [M-H]- |  |
| 987.7787 | Loss of inositol from [M-H]- |  |
| 837.5862 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 819.5757 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 675.5334 | Loss of sn2 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 657.5229 | Neutral loss of sn2 RCOOH group and inositol from [M-H]- |  |
| 645.3045 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 627.2940 | Neutral loss of sn1 RCOOH group from [M-H]- |  |
| 521.5303 | sn1 RCOO- ion |  |
| 483.2517 | Loss of sn1 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 465.2412 | Neutral loss of sn1 RCOOH group and inositol from [M-H]- |  |
| 329.2486 | sn2 RCOO- ion |  |
| 315.0487 | Glycerophosphoinositol -H2O |  |
| 297.0381 | Glycerophosphoinositol -2H2O |  |
| 285.2588 | Loss of CO2 from sn2 RCOO- ion (PUFA) |  |
| 259.0225 | Inositol phosphate ion |  |
| 241.0119 | Inositol phosphate ion - H2O |  |
| 223.0013 | Inositol phosphate ion - 2 H2O |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |