Structure Database (LMSD)

Common Name
PE-N[FA 20:4(5Z,8Z,11Z,14Z)] P-18:0/18:1(9Z)
Systematic Name
1-(1Z-octadecenyl)-2-(9Z-octadecenoyl)-glycero-3-phospho-N-5Z,8Z,11Z,14Z-eicosatetraenoyl-ethanolamine
Synonyms
  • 1-(1Z-octadecenyl)-2-(oleoyl)-sn-glycero-3-phospho-N-arachidonoyl-ethanolamine
  • NAPE(P-16:0/18:1(9Z)/20:4(5Z,8Z,11Z,14Z))
LM ID
LMGP02030098
Formula
Exact Mass
Calculate m/z
1015.796907
Sum Composition
Status
Active

Classification

References

Taxonomy Information

Curated from
NCBI taxonomy class
Reference
Rattus norvegicus (#10116)
Mammalia (#40674)
Identification of biosynthetic precursors for the endocannabinoid anandamide in the rat brain.,
J Lipid Res, 2008
Pubmed ID: 17957091

String Representations

InChiKey (Click to copy)
HJOKRGRSYJFCBV-TVBQABSRSA-N
InChi (Click to copy)
InChI=1S/C61H110NO8P/c1-4-7-10-13-16-19-22-25-28-30-32-34-37-40-43-46-49-52-60(63)62-54-56-68-71(65,66)69-58-59(57-67-55-51-48-45-42-39-36-33-29-26-23-20-17-14-11-8-5-2)70-61(64)53-50-47-44-41-38-35-31-27-24-21-18-15-12-9-6-3/h16,19,25,27-28,31-32,34,40,43,51,55,59H,4-15,17-18,20-24,26,29-30,33,35-39,41-42,44-50,52-54,56-58H2,1-3H3,(H,62,63)(H,65,66)/b19-16-,28-25-,31-27-,34-32-,43-40-,55-51-/t59-/m1/s1
SMILES (Click to copy)
[C@](COP(=O)(O)OCCNC(CCC/C=C\C/C=C\C/C=C\C/C=C\CCCCC)=O)([H])(OC(CCCCCCC/C=C\CCCCCCCC)=O)CO/C=C\CCCCCCCCCCCCCCCC

Other Databases

PubChem CID

Calculated Physicochemical Properties

Heavy Atoms 71
Rings 0
Aromatic Rings 0
Rotatable Bonds 56
Van der Waals Molecular Volume 1143.89
Topological Polar Surface Area 120.39
Hydrogen Bond Donors 2
Hydrogen Bond Acceptors 9
logP 20.33
Molar Refractivity 304.83

Admin

Created at
6th Oct 2023
Updated at
6th Oct 2023
LIPID MAPS® abbreviations for glycerophospholipids (GP)

The LIPID MAPS® glycerophospholipid abbreviations (PC, PE, etc.) are used here to refer to species with one or two radyl side-chains where the structures of the side chains are indicated within parentheses in the 'Headgroup(sn1/sn2)' format (e.g. PC(16:0/18:1(9Z)). By default, R stereochemistry at the C-2 carbon of glycerol and attachment of the headgroup at the sn3 position is assumed. Also, acyl chains are assumed by default. The 'O-' prefix is used to indicate the presence of an alkyl ether substituent e.g. PC(O-16:0/18:1(9Z)), whereas the 'P-' prefix is used for the 1Z-alkenyl ether (Plasmalogen) substituent e.g. PC(P-16:0/18:1(9Z)).

For molecules with opposite (S) stereochemistry at C2 of the glycerol group and attachment of the headgroup at the sn1 position, the stereochemistry specification of [S] is appended to the abbreviation. The 'Headgroup(sn3/sn2)' abbreviation format is used.

For molecules with unknown stereochemistry at the C-2 carbon of the glycerol group, the stereochemistry specification of [U] is appended to the abbreviation and the structure is drawn with C-2 stereochemistry unspecified.