LIPID MAPS

Structure Database (LMSD)

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Common Name

1,9-dideoxyforskolin

Systematic Name

(3R,4aS,5S,6S,6aS,10aS,10bR)-3-ethenyl-6-hydroxy-3,4a,7,7,10a-pentamethyl-1-oxododecahydro-1H-benzo[f]chromen-5-yl acetate

Synonyms

(3R,4aS,5S,6S,6aS,10aS,10bR)-5-(acetyloxy)-3-ethenyldodecahydro-6-hydroxy-3,4a,7,7,10a-pentamethyl-1H-naphtho(2,1-b)pyran-1-one
(3R-(3alpha,4abeta,5beta,6beta,6aalpha,10abeta,10balpha))-5-(acetyloxy)-3-ethenyldodecahydro-6-hydroxy-3,4a,7,7,10a-pentamethyl-1H-naphtho(2,1-b)pyran-1-one
7beta-acetoxy-8,13-epoxy-6beta-hydroxylabd-14-en-11-one

LM ID

LMPR0104030009

Formula

C₂₂H₃₄O₅

Exact Mass

Calculate m/z

378.240625

Status

Curated

Show lipids differing only in stereochemistry/bond geometry

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Classification

References

Taxonomy Information

Curated from

NCBI taxonomy class

Reference

Plectranthus barbatus (#41228)

Magnoliopsida (#3398)

Structures and stereochemistry of new labdane diterpiniods from coleus forskohlii briq.,
Tetrahedron Letts, 1977

DOI: 10.1016/S0040-4039(01)93245-9

String Representations

InChiKey (Click to copy)

ZKZMDXUDDJYAIB-SUCLLAFCSA-N

InChi (Click to copy)

InChI=1S/C22H34O5/c1-8-20(5)12-14(24)16-21(6)11-9-10-19(3,4)17(21)15(25)18(26-13(2)23)22(16,7)27-20/h8,15-18,25H,1,9-12H2,2-7H3/t15-,16+,17-,18-,20-,21+,22-/m0/s1

SMILES (Click to copy)

C1C([C@]2([C@]([C@@]3([H])C(=O)C[C@@](C)(O[C@]3(C)[C@H]([C@H]2O)OC(C)=O)C=C)(C)CC1)[H])(C)C